✦ LIBER ✦

Synthesis and characterization of iridium chloride complexes: I. Use ofN-alkylphenothiazine drugs as ligands

✍ Scribed by Netkal M. Made Gowda; Myint M. Kyi; Libo Zhang

Publisher: Springer
Year: 1993
Tongue: English
Weight: 441 KB
Volume: 18
Category: Article
ISSN: 0340-4285
DOI: 10.1007/bf00136618

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✦ Synopsis

Iridium complexes of N-alkylphenothiazines have been prepared in MeOH. The polynuclear complexes obtained have been characterized by elemental analyses, magnetic susceptibilities, molar conductivities, thermogravimetric analysis and spectral data. The molecular formulae of the new complexes are as follows: [Ir3(LH)4Cllo]C1 z'xMeOH, where L = chlorpromazine (CP), promethazine (PM) or ethopropazine (EP), and x = 1 for CP and 2 for PM or EP; [Ir(TFH2)2C14] [IrC161" MeOH, where TF = trifluoperazine; and [Ir3(TRH)2C1 ll(MeOH)]CI'MeOH and [Ir4(TRH)3ClIs], where TR=thioridazine. The complexes are diamagnetic in nature. Tentative structures are proposed for the complexes.

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