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Synthesis and Characterization of Imidazolate-Bridged Dinuclear Complexes as Active Site Models of Cu,Zn-SOD

โœ Scribed by Ohtsu, Hideki; Shimazaki, Yuichi; Odani, Akira; Yamauchi, Osamu; Mori, Wasuke; Itoh, Shinobu; Fukuzumi, Shunichi


Book ID
120336520
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
224 KB
Volume
122
Category
Article
ISSN
0002-7863

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A new route to bimetallic azine-bridged
โœ Bachcha Singh; Ashutosh K. Srivastav ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› Springer ๐ŸŒ English โš– 461 KB

A novel unsymmetrical tetradentate azine, 2-acetylpyridinesalicylaldazine (Haps), was prepared by condensing salicylhydrazone with 2-acetylpyridine, and was characterized by elemental analysis and its i.r. spectrum. This ligand reacted with Mn, Co, Ni, Cu and Zn acetates to yield deprotonated M(aps)