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Synthesis and characterization of high molecular weight perfluorocyclobutyl-containing polybenzimidazoles (PFCB–PBI) for high temperature polymer electrolyte membrane fuel cells

✍ Scribed by Guoqing Qian; Dennis W. Smith Jr.; Brian C. Benicewicz


Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
268 KB
Volume
50
Category
Article
ISSN
0032-3861

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## Abstract A series of polybenzimidazoles (PBIs) incorporating main chain pyridine groups were synthesized from the pyridine dicarboxylic acids (2,4‐, 2,5‐, 2,6‐ and 3,5‐) and 3,3′,4,4′‐tetraaminobiphenyl, using polyphosphoric acid (PPA) as both solvent and polycondensation reagent. A novel proces