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Synthesis and characterization of extremely bulky amido-germanium(II) halide complexes

✍ Scribed by Hadlington, Terrance J.; Li, Jiaye; Jones, Cameron

Book ID
125519534
Publisher
NRC Research Press
Year
2014
Tongue
French
Weight
418 KB
Volume
92
Category
Article
ISSN
0008-4042

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Both 1 : 1 and 1 : 2 complexes are formed by zinc(II) halides and triarylphosphines unless electronic and/or steric factors intervene. Tri-p-chlorophosphine (a weaker base than PPh 3 ) forms only a 1 : 1 complex, whereas bulky tri-(ortho-substituted phenyl)phosphines do not react. The complexes ZnX