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Synthesis and characterization of dinuclear platinum group metal complexes of a hexadentate ligandα,α′-bis(bis-(2-(diphenylphosphino)ethyl)amino)-m-xylene

✍ Scribed by Parimal Paul; Beena Tyagi

Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
649 KB
Volume
15
Category
Article
ISSN
0277-5387

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✍ Giuseppe Battaini; Luigi Casella; Michele Gullotti; Enrico Monzani; Giorgio Nard 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 185 KB

## Abstract The ligand α,α′‐bis{bis[1‐(1′‐methyl‐2′‐benzimidazolyl)methyl]amino}‐__m__‐xylene (L‐55) forms the complexes [Cu^I^~2~(L‐55)(MeCN)~2~](PF~6~)~2~ (1) and [Cu^II^~2~(L‐55)(OMe)~2~][ClO~4~]~2~ (2), in which an extremely weak axial amine interaction is imposed by the small five‐membered ben