Synthesis and Characterization of Dimethylbis(2-pyridyl)borate Nickel(II) Complexes: Unimolecular Square-Planar to Square-Planar Rotation around Nickel(II)
β Scribed by Celaje, Jeff A.; Pennington-Boggio, Megan K.; Flaig, Robinson W.; Richmond, Michael G.; Williams, Travis J.
- Book ID
- 127154787
- Publisher
- American Chemical Society
- Year
- 2014
- Tongue
- English
- Weight
- 935 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0276-7333
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π SIMILAR VOLUMES
The reaction of [NBu(4)](2)[Ni(C(6)F(5))(4)] (1) with solutions of dry HCl(g) in Et(2)O results in the protonolysis of two Nibond;C(6)F(5) bonds giving [NBu(4)](2)[[Ni(C(6)F(5))(2)](2)(mu-Cl)(2)] (2 a) together with the stoichiometrically required amount of C(6)F(5)H. Compound 2 a reacts with AgClO(
## Abstract Nickel(II) complexes comprising electronically delocalised __N__,__O__βchelating ligands are active catalysts in the copolymerisation of carbon monoxide and ethene. Elucidating the mechanism of catalysis presupposes the basic understanding of the intramolecular flexibility of such trans