Synthesis and characterization of degradable copoly(trans-4-hydroxy-L-proline/ϵ-caprolactone)
✍ Scribed by Ren-Shen Lee; Jen-Ming Yang
- Publisher
- John Wiley and Sons
- Year
- 2003
- Tongue
- English
- Weight
- 102 KB
- Volume
- 88
- Category
- Article
- ISSN
- 0021-8995
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The synthesis of hydroxyproline-based telechelic prepolymers by the condensation polymerization of trans-4-hydroxy-N-benzyloxycarbonyl-L-proline methyl ester was investigated. All the polymerizations were carried out in the melt with stannous octoate as the catalyst and with different diols. The pro
A series of novel copolymers of trans-4-hydroxy-L-proline (Hpr) and ␣hydroxy acids [D,L-mandelic acid (DLMA) and D,L-lactic acid (DLLA)] were synthesized via direct melt copolymerization with stannous octoate as a catalyst. These new copolymers had pendant amine functional groups along the polymer b