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Synthesis and characterization of cis-bis[(p-tolylsulfonyl)methyl]palladium(II) complexes

✍ Scribed by Pablo Espinet; Jesús M. Martínez-Ilarduya; Celeste Peŕez-Briso


Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
706 KB
Volume
447
Category
Article
ISSN
0022-328X

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Three new monomeric complexes of palladium(II) azide with 2-chloropyridine (1), 3-chloropyridine (2), and quinoline (3), have been synthesized by reaction of palladium nitrate and the respective Lewis-base with sodium azide in a water/acetone mixture. All three compounds were characterized by IR, Ra