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Synthesis and Characterization of Chiral Periodic Mesoporous Organosilicas

✍ Scribed by Xiangju Meng; Toshiyuki Yokoi; Daling Lu; Takashi Tatsumi


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
483 KB
Volume
119
Category
Article
ISSN
0044-8249

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## Abstract The first synthesis of a chiral periodic mesoporous organosilica (PMO) carrying benzylic ether bridging groups is reported. By hydrolysis and condensation of the new designed chiral organosilica precursor 1,4‐bis(triethoxysilyl)‐2‐(1‐methoxyethyl)benzene (BTEMEB) in the presence of the

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## Abstract In this study we report the synthesis of a new class of materials called hybrid periodic mesoporous organosilicas (HPMOs). ByΒ coupling a silsesquioxane precursor through at least two chemical linkages to the mesopore walls of a pre‐existing periodic mesoporous silica (PMS) or periodic m