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Synthesis and characterization of bis[difluorooxychlorine(V)] hexafluoronickelate(IV), (ClF2O)2NiF6

✍ Scribed by Wilson, William W.; Christe, Karl O.


Book ID
127242628
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
276 KB
Volume
23
Category
Article
ISSN
0020-1669

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## Abstract An all‐inorganic complex, [Mn~2~{(VO~3~)~5~}~2~]^6–^ (1), was synthesized, and the structure determination reveals a dinuclear manganese complex coordinated by two cyclic pentavanadate ligands. The cyclic pentavanadate units sandwich the edge‐sharing octahedral dimanganese core through