✦ LIBER ✦

Synthesis and characterization of authentic standards for the analysis of ribofuranose-containing carbohydrates by the reductive-cleavage method

✍ Scribed by Christine R. Rozanas; Nan Wang; Kathy Vidlock; Gary R. Gray

Publisher: Elsevier Science
Year: 1995
Tongue: English
Weight: 553 KB
Volume: 274
Category: Article
ISSN: 0008-6215
DOI: 10.1016/0008-6215(95)00096-c

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✦ Synopsis

Described herein is the synthesis of all positional isomers of partially methylated and acetylated or benzoylated 1,4-anhydro-D-ribitol. The benzoates are generated simultaneously from 1,4-anhydro-D-ribitol by sequential partial methylation and benzoylation or sequential partial benzoylation and methylation. The individual isomers are obtained in pure form by high-performance liquid chromatography. Debenzoylation and acetylation provided the corresponding acetates. Reported herein are the IH NMR spectra of the benzoates and the electron-ionization mass spectra of the acetates and the tri-O-methyl derivative and also for the acetates and the tri-O-methyl derivative, their linear temperature programmed gas-liquid chromatography retention indices on three different capillary columns.

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