Synthesis and Characterization of Aluminum-Containing Tin(IV) Heterobimetallic Sulfides
✍ Scribed by Yang, Zhi; Ma, Xiaoli; Jancik, Vojtech; Zhang, Zhensheng; Roesky, Herbert W.; Magull, Jörg; Noltemeyer, Mathias; Schmidt, Hans-Georg; Cea-Olivares, Raymundo; Toscano, Rubén A.
- Book ID
- 127344650
- Publisher
- American Chemical Society
- Year
- 2006
- Tongue
- English
- Weight
- 158 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0020-1669
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📜 SIMILAR VOLUMES
A mononuclear precursor complex, [(CH 3 ) 2 Sn(tpdtc)] and several of its heterobimetallic derivatives of the type, [(CH 3 ) 2 Sn(tpdtc)]MCl 2 have been synthesized by the simple addition reaction of transition metal chlorides, MCl 2 ÁnH 2 O where tpdtc = tetraethylenepentamine bis(dithiocarbamate)
## Abstract 12‐Chloro‐12‐n‐butyl‐1,11‐dioxa‐4,8‐ dithia‐12‐stannacyclododecane (**3a**) and 12‐chloro‐ 12‐n‐butyl‐1,4,8,11‐tetrathia‐12‐stannacyclododecane (**3b**) have been prepared by reacting n‐butyltin trichloride with 1,11‐dioxa‐4,8‐dithiaundecane and 1,4,8,11‐tetrathiaundecane, respectively.