Synthesis and characterization of alkene-extended tetrathiafulvalenes with lateral alkyne appendages

✍ Scribed by Mogens Brøndsted Nielsen; Jean-Paul Gisselbrecht; Niels Thorup; Stefano P. Piotto; Corinne Boudon; Maurice Gross

• Book ID: 104254243
• Publisher: Elsevier Science
• Year: 2003
• Tongue: French
• Weight: 185 KB
• Volume: 44
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(03)01645-9

✦ Synopsis

Tetrathiafulvalene (TTF) derivatives containing a diethynyl-substituted alkene spacer were synthesized and investigated for their electronic and structural properties. Co-planarity of the central diethynylethene unit and the two dithiole rings were confirmed by X-ray crystallographic analysis.