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Synthesis and characterization of a series of star-branched poly(ε-caprolactone)s with the variation in arm numbers and lengths

✍ Scribed by Jeongsoo Choi; In-Ki Kim; Seung-Yeop Kwak

Book ID
108248226
Publisher
Elsevier Science
Year
2005
Tongue
English
Weight
410 KB
Volume
46
Category
Article
ISSN
0032-3861

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## Abstract The kinetics and controllability of the Ti[OCH~2~CCl~3~]~4~‐initiated atom transfer radical polymerization (ATRP) of __n__‐butyl acrylate were investigated. Then, with Ti[OCH~2~CCl~3~]~4~ as the initiator, poly(ϵ‐caprolactone)‐__block__‐poly(__n__‐butyl acrylate) (PCL‐__b__‐PBA) copolym