A new chelating ion-exchange resin containing the hydroxamic acid functional group was synthesized from poly(methyl acrylate) (PMA)-grafted sago starch. The PMA grafted copolymer was obtained by a free-radical initiating process in which ceric ammonium nitrate was used as an initiator. Conversion of
Synthesis and characterization of a poly(aminophosphonic acid) chelating resin
β Scribed by M.C. Yebra-Biurrun; A. Bermejo-Barrera; M.P. Bermejo-Barrera
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 510 KB
- Volume
- 264
- Category
- Article
- ISSN
- 0003-2670
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β¦ Synopsis
Prehmmary mvesttgatlons on the apphcatlon of a polystyrene macroretlcular, cross-lmked poly(ammophosphomc acld) resm for the concentration of trace metals from aqueous solutions are reported The pH dependence of metal-resm chelation was determmed for M&I), Ca(II), Fe(III), CrtIII), N1(11), Cu(II), Pb(II), Zn(II) and M&I) The resm exhlblts no affnuty for the alkah metals tested over the pH range 1-14 The resm selectlvlty and capacity were determmed at pH 5 Metals were easily recovered by elutlon with 3 M hydrochloric acid and determmed m the eluate by flame atomx absorption spectrometry
π SIMILAR VOLUMES
In this article, a new synthetic approach to a 1,4,2-oxazaphosphorinane, and to β£-ethyl-β£-N-(hydroxyethylamino)methyl phosphonicacid and their sodium salts is described. The title compounds were characterized by NMR and FAB spectroscopy.