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Synthesis and Characterization of a Novel Class of Dicopper(I) Bis(carboxylate)-Bridged Complexes

โœ Scribed by LeCloux, Daniel D.

Book ID
121497134
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
473 KB
Volume
36
Category
Article
ISSN
0020-1669

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The two dinuclear Ir I complexes [Ir 2 (m-Cl) ) smoothly react with 4 equiv. of the lithium salt of aniline to afford the new bis(anilido)iridate(I) ( bis(benzenaminato)iridate(1-)) complexes Li[Ir(NHPh) 2 {(R)-(S)-PPF-PPh 2 }] (4) and Li[Ir(NHPh) 2 {(R)-binap}] (5), respectively. The anionic compl