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Synthesis and characterization of a new nonlinear optical single crystal: L-Lysinium trifluoroacetate

✍ Scribed by V. Mathivanan; T. Raghavalu; M. Kovendhan; K. Suriya Kumar; S. Gokul Raj; G. Ramesh Kumar; R. Mohan


Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
113 KB
Volume
43
Category
Article
ISSN
0232-1300

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✦ Synopsis


Single crystals of a new L-Lysine salt: L-Lysinium trifluoroacetate {abbreviated as LLyTFA; [(NH 2 )-(CH 2 ) 4 -CH-(NH 3 )-(COOH)] + CF 3 COO -} were grown by slow evaporation of an aqueous solution at room temperature. The grown crystals were subjected to single crystal X-ray diffraction, FTIR and UV-Vis-NIR spectrum analyses. The UV-Vis-NIR spectrum shows that the absorption is very less in the whole of the region from ultraviolet to near IR. The Kurtz-Perry powder SHG measurement using a Nd:YAG laser of wavelength 1064nm confirms the frequency doubling of the crystal and its powder SHG efficiency was measured as d eff = 0.96 d eff (KDP).


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