Synthesis and Characterization of 3,3′-Azobis(6-Amino-1,2,4,5-Tetrazine) DAAT – A New Promising Nitrogen-Rich Compound
✍ Scribed by Jochen Kerth; Stefan Löbbecke
- Publisher
- John Wiley and Sons
- Year
- 2002
- Tongue
- English
- Weight
- 315 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0721-3115
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The novel and versatile cyanomethyl 2amino-4-methylthiazolyl ketone (5) was prepared by treatment of bromomethyl 2-amino-4-methyl thiazolyl ketone (4) with potassium cyanide. Reaction of 5 with heterocyclic diazonium salts 6a,b and 10 afforded the corresponding hydrazones 7a,b and 11, respectively.
## Reactions of [(AMTTO)PdCl 2 ]•MeOH (1) with sodium bromide and sodium iodide led to the palladacycles [(AMTTO)PdBr 2 ] 2 •3.5THF (2) and [(AMTTO)PdI 2 ] 2 •3MeOH (3) in excellent yields. Treatment of 2 and 3 with triphenylphosphane gave the complexes [(AMTTO)Pd(PPh 3 )Br]-Br•MeOH (4) and [(AMTT