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Synthesis and characterization of 1,6,11-triazacyclopentadecane and its zinc(II) complex

✍ Scribed by Kazuhiko Ida; Hisashi Ōkawa; Hiroshi Sakiyama; Masahito Kodera; Sigeo Kida; Ichiro Murase


Book ID
108327954
Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
459 KB
Volume
184
Category
Article
ISSN
0020-1693

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Both 1 : 1 and 1 : 2 complexes are formed by zinc(II) halides and triarylphosphines unless electronic and/or steric factors intervene. Tri-p-chlorophosphine (a weaker base than PPh 3 ) forms only a 1 : 1 complex, whereas bulky tri-(ortho-substituted phenyl)phosphines do not react. The complexes ZnX