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Synthesis and Characterization of 1,2-bis(2′-Pyrazineethynyl) Benzene Palladium(II) Dichloride and Its Catalysis of the Suzuki Coupling Reaction.

✍ Scribed by Nate Schultheiss; Charles L. Barnes; Eric Bosch


Publisher
John Wiley and Sons
Year
2004
Weight
104 KB
Volume
35
Category
Article
ISSN
0931-7597

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Three new monomeric complexes of palladium(II) azide with 2-chloropyridine (1), 3-chloropyridine (2), and quinoline (3), have been synthesized by reaction of palladium nitrate and the respective Lewis-base with sodium azide in a water/acetone mixture. All three compounds were characterized by IR, Ra