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Synthesis and Characterisation of the Sodium and Lithium Cryptates of Macrobicyclic Ligands incorporating pyridine, bipyridine, and biisoquinoline units

✍ Scribed by Béatrice Alpha; Elke Anklam; Robert Deschenaux; Jean-Marie Lehn; Marek Pietraskiewiez


Publisher
John Wiley and Sons
Year
1988
Tongue
German
Weight
759 KB
Volume
71
Category
Article
ISSN
0018-019X

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📜 SIMILAR VOLUMES


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## Abstract The crystal structures of the LiBr complexes of two macrobicyclic ligands, [py.py.bpy]1 and [py.biqi.biqi] 2, have been determined. They confirm the cryptate nature of these species. In 3, the Li^+^ cation is bound in the shallow cavity of a ligand of flattened shape, whereas in 4, it i

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## Abstract The NaBr cryptates of five macrobicyclic ligands containing bipyridine (bpy) and phenanthroline (phen) groups, __i.e__, of [bpy.bpy.bpy] **1** [bpy.bpy.phen] **2** [phen.phen.‐phen] **3** [2.1.phen] **4** and [2.2.phen] **5**, have been prepared. **1, 2, 4** and **5** have been obtained