Photo-transformation of G, C,,,, C,O, and C,Os in toluene results in destruction of these species. CW and CT0 are transformed with equal rates to form C,O and C,OO. No higher oxides of these fullerenes are formed. C,O is destroyed twice as fast and &,,02 approximately 40-50 times faster than Cs Prod
Synthesis and characterisation of the methanofullerenes, C60(CHCN) and C60(CBr2)
β Scribed by Ana M. Benito; Adam D. Darwish; Harold W. Kroto; Mohammed F. Meidine; Roger Taylor; David R.M. Walton
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- French
- Weight
- 136 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0040-4039
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We describe the HPLC separation and identification of N@C60 and N2@C60. These species were observed after eleven sequential HPLC separations. Their retention times are in the same range as those of the other noninteractive endohedral species of C60, such as noble gas endohedral C60. The separation f
Electronic structures of the icosahedral C&H,,, hydrocarbon and its perfhroro analog, C6nF6,,, are examined at the HF/4-31G and HF/6-3 lG\*\* levels. The calculated C-C bond lengths are as large as 1.57 A in C63Hb0 and 1.63 A in CbDF60. The bond lengthening is attributed to the H-H and F-F steric in