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Synthesis and Characterisation of Tetrathiafulvalenyl- and Ferrocenyl-Triphenylenes

✍ Scribed by Graeme Cooke; Abdulla Radhi; Neville Boden; Richard J Bushby; Zhibao Lu; Sarah Brown; Sarah L Heath

Book ID: 104202665
Publisher: Elsevier Science
Year: 2000
Tongue: French
Weight: 161 KB
Volume: 56
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(00)00250-7

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The aldimines FcCH=NCH(Me)CH 2 OMe (1), FcCH=NCH 2 H 6 H 4 -2-OMe (2) and FcCH=N(CH 2 ) 3 NHMe (3) were obtained by reacting ferrocene aldehyde with the corresponding primary amines. Compounds 1±3 react with Me 2 Zn and Me 3 Al in a molar ratio 1 : 1 to the corresponding adducts 4±8. Reactions of 1