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Synthesis and Characterisation of New Metallacycles Containing [Ph 2 P(E)NP(E)Ph 2 ] − (E = S OR Se) Ligands

✍ Scribed by Slawin, Alexandra M. Z.; Smith, Martin B.

Book ID: 126582823
Publisher: Taylor and Francis Group
Year: 1997
Tongue: English
Weight: 151 KB
Volume: 124
Category: Article
ISSN: 1042-6507
DOI: 10.1080/10426509708545664

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The ligands [Ph 2 (S)PNHP(X)Ph 2 ] -(X = O, Se) react with InCl 3 coordination geometry in 2 resembles that observed in the three analogous tris-chelates incorporating the corres-in a 3:1 ratio to give a tris-chelate [In{Ph 2 P(O)NP(S)Ph 2 -O,S} 3 ]•0.75 C 6 H 6 (2) and the unexpected pentacoordinat