Synthesis and Characterisation of Macrobicyclic Tetrathiafulvalene-Bridged Cage Molecules

✍ Scribed by Philippe Blanchard; Niels Svenstrup; Joëlle Rault-Berthelot; Amédée Riou; Jan Becher

• Book ID: 102658370
• Publisher: John Wiley and Sons
• Year: 1998
• Tongue: English
• Weight: 647 KB
• Volume: 1998
• Category: Article
• ISSN: 1434-193X
• DOI: 10.1002/(sici)1099-0690(199809)1998:9<1743::aid-ejoc1743>3.0.co;2-j

✦ Synopsis

A series of new macrobicyclic tetrathiafulvalenophanes of by cyclic voltammetry. An electrochemical investigation using the Bard-Anson equation and thin-layer cyclic type 1 and 2 with three tetrathiafulvalene bridges has been prepared under high-dilution conditions using a stepwise voltammetry has been carried out, allowing an estimate of the number of electrons involved in each redox process of selective protection-deprotection of tetrathiafulvalenethiolates. All the macrobicyclic tetrathiafulvalenes, along these multi-redox compounds. The X-ray crystal structure showing the unusual crystal packing of 2a is also presented. with the intermediate compounds 5 and 6 and the unexpected tetrathiafulvalene pentamers 17, were studied