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Synthesis and Characterisation of a New Series of Bistable Iron(II) Spin-Crossover 2D Metal–Organic Frameworks

✍ Scribed by Víctor Martínez; Ana Belén Gaspar; M. Carmen Muñoz; Gennadiy V. Bukin; Georgii Levchenko; José Antonio Real

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
525 KB
Volume
15
Category
Article
ISSN
0947-6539

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## Abstract The reaction of CuCl~2~**·**2H~2~O with three novel ditopic ligands, 2‐methyl‐1,4‐benzeneditetrazolate (MeBDT^2–^), 4,4′‐biphenylditetrazolate (BPDT^2–^), and 2,3,5,6‐tetrafluoro‐1,4‐benzeneditriazolate (TFBDTri^2–^), affords the metal–organic frameworks Cu(MeBDT)(dmf) (**1**), Cu(BPDT)