𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis and catalytic properties of rhodium(I) complexes with anionic chelate nitrogen-oxygen ligands

✍ Scribed by Wanzhi Chen; Yun Xu; Shijian Liao

Publisher
Springer
Year
1994
Tongue
English
Weight
256 KB
Volume
19
Category
Article
ISSN
0340-4285

No coin nor oath required. For personal study only.

✦ Synopsis

Dicarbonyl complexes of rhodium(I) [Rh(CO)2(LL')],

where LL' ~-salicylaldoximate, 8-oxyquinolinate, glycinate, leucinate, aminophenolate or pyridine carboxylate and [Rh(COD)(LL')], where COD = 1,5-cyclooctadiene, were prepared and characterized by elemental analysis, and i.r. and n.m.r, spectra. Their activity to catalytic hydroformylation of styrene has been evaluated at atmospheric pressure of CO:H2 (1 : 1).

πŸ“œ SIMILAR VOLUMES

Synthesis and Properties of Complexes of
Synthesis and Properties of Complexes of Vanadium(V) Oxide Trichloride with Nitrogen- and Oxygen-Donor Ligands
✍ Charlotte D. Beard; Rosalind J. Barrie; John Evans; William Levason; Gillian Rei πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 154 KB

## Abstract Intensely coloured, extremely moisture sensitive complexes [VOCl~3~(L)] (L = pyridine, quinoline, Ph~3~PO, Ph~3~AsO, pyridine __N__‐oxide), [VOCl~3~(L)~2~] (L = pyridine, Me~3~PO, pyridine __N__‐oxide), [VOCl~3~(L–L)] [L–L = 2,2′‐bipyridyl, 1,10‐phenanthroline, Ph~2~P(O)CH~2~P(O)Ph~2~,