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Synthesis and Catalytic Properties of Di- and Trinuclear Palladium Complexes with PCP-Pincer Ligands

✍ Scribed by I. P. Beletskaya; A. V. Chuchuryukin; G. van Koten; H. P. Dijkstra; G. P. M. van Klink; A. N. Kashin; S. E. Nefedov; I. L. Eremenko


Book ID
111609030
Publisher
SP MAIK Nauka/Interperiodica
Year
2003
Tongue
English
Weight
179 KB
Volume
39
Category
Article
ISSN
1070-4280

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## Abstract **Feel the pinch!** Planar–chiral, cationic, ruthenium–palladium complexes based on η^6^,η^1^‐coordinated ECE′ pincer ligands are synthesized as racemic mixtures by reacting ECE′–palladium complexes and [Ru(C~5~R~5~)(MeCN)~3~]^+^ arenophiles (R=H or Me). Chiral resolution of the cationi