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Synthesis and catalytic properties of crystalline, microporous vanadium silicates with MEL structure

✍ Scribed by P.R. Hari Prasad Rao; A.V. Ramaswamy; P. Ratnasamy

Book ID
113180548
Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
485 KB
Volume
137
Category
Article
ISSN
0021-9517

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The transformation of ethanol was carried out over vanadium silicate molecular sieves with MEL topology (VS-2) with different Si/V atomic ratios in the temperature range 523-623 K. The reaction was performed in a fixed-bed down-flow reactor at atmospheric pressure. Acetaldehyde, diethyl ether, and e

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Vanadium silicate molecular sieves with MEL structure (VS-2) are found to be active in the hydroxylation of phenol with hydrogen peroxide, a reaction which is commercially practiced over titanium silicalite (TS-1 and TS-2) catalysts. Among various reaction parameters, the influence of the solvent on