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Synthesis and catalytic properties in olefin epoxidation of dioxomolybdenum(vi) complexes bearing a bidentate or tetradentate salen-type ligand

✍ Scribed by Sofia M. Bruno; Salete S. Balula; Anabela A. Valente; Filipe A. Almeida Paz; Martyn Pillinger; Carla Sousa; Jacek Klinowski; Cristina Freire; Paulo Ribeiro-Claro; Isabel S. Gonçalves

Publisher
Elsevier Science
Year
2007
Tongue
English
Weight
407 KB
Volume
270
Category
Article
ISSN
1381-1169

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Synthesis and catalytic properties in ol
Synthesis and catalytic properties in olefin epoxidation of chiral oxazoline dioxomolybdenum(VI) complexes
✍ Sofia M. Bruno; Bernardo Monteiro; Maria Salete Balula; Filipe M. Pedro; Marta A 📂 Article 📅 2006 🏛 Elsevier Science 🌐 English ⚖ 210 KB

Dioxomolybdenum(VI) complexes with the general formula [MoO 2 X 2 (N,N)] (X = Cl, OSiPh 3 ) containing a chiral bidentate oxazoline ligand (N,N = 2,2 -bis[(4S)-4-benzyl-2-oxazoline]) have been prepared and characterised by 1 H NMR, IR spectroscopy and thermogravimetric analysis. The bis(chloro) comp