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Synthesis and catalytic hydrogenolysis of 1,1,2-trimethylcyclopropane

✍ Scribed by B. A. Kazansky; M. Yu. Lukina; V. A. Ovodova


Book ID
112490995
Publisher
Springer
Year
1954
Tongue
English
Weight
236 KB
Volume
3
Category
Article
ISSN
1573-9171

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## Abstract The Arrhenius parameters for the gas phase, unimolecular structural isomerizations of 1,1,2‐trimethylcyclopropane to three isomeric methylpentenes and two dimethylbutenes have been determined over a wide range of temperatures, 688–1124 K, using both static and shock tube reactors. For t

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The gas-phase reaction kinetics of 1,1,2-trimethylcyclopropane have been studied in First-order unimolecular rate constants for overthe temperature range of 70Cb755"K. all reactant disappearance fit the Arrhenius equation 61.08 f 0.51 log ko (sec-l) = 14.47e Reaction products and the relative rates