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Synthesis and catalytic activity of new macrocyclic chiral salen complexes

✍ Scribed by Geon-Joong Kim; Dae-Woon Park; Yong-Sug Tak

Book ID
110383231
Publisher
Springer US
Year
2000
Tongue
English
Weight
119 KB
Volume
65
Category
Article
ISSN
1011-372X

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Catalytic activity and recyclability of
Catalytic activity and recyclability of new enantioselective chiral Co–salen complexes in the hydrolytic kinetic resolution of epichlorohydrine
✍ Geon-Joong Kim; Hosung Lee; Seong-Jin Kim πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 French βš– 348 KB

Chiral Co(III) salen catalysts bearing PF 6 , BF 4 or Br counterions proved to be reactive and enantioselective in the hydrolytic resolution of terminal epoxides. The catalysts could be recovered and reused several times without further treatment after reaction, showing no loss of activity and enant