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Synthesis and Catalytic Activity of a Fluorous-Tagged TEMPO Radical.

✍ Scribed by Gianluca Pozzi; Marco Cavazzini; Orsolya Holczknecht; Silvio Quici; Ian Shepperson

Publisher
John Wiley and Sons
Year
2004
Weight
103 KB
Volume
35
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

For Abstract see ChemInform Abstract in Full Text.

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✍ Simonβ€…D. Nielsen; Garrick Smith; Mikael Begtrup; Jesperβ€…L. Kristensen πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons 🌐 English βš– 344 KB πŸ‘ 2 views

## Abstract A novel fluorous‐tagged ammonia equivalent has been developed. It is based on a nitrogen–oxygen bond, which can be cleaved in a traceless manner by a molybdenum complex or samarium diiodide. The application in the synthesis of ureas, amides, sulfonamides, and carbamates is described. Th