## Abstract **Summary:** Well‐defined pentablock copolymers of styrene–[1]dimethylsilaferrocenophane–methyl methacrylate (PMMA‐__b__‐PFS‐__b__‐PS‐__b__‐PFS‐__b__‐PMMA) are synthesized using lithium naphthalide as initiator and a 1,1‐dimethylsilacyclobutane‐mediated 1,1‐diphenylethylene (DPE) end‐ca
Synthesis and Bulk Morphology of Styrene-ferrocenylsilane-methyl Methacrylate Tri- and Pentablock Copolymers
✍ Scribed by Christian Kloninger; Uttam Datta; Matthias Rehahn
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 11 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
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## Abstract Triblock copolymers were synthesized from styrene (S), dimethylsilaferrocenophane (FS), and methyl methacrylate (MMA) via sequential anionic polymerization, taking advantage of the dimethylsilacyclobutane‐mediated endcapping of the living PS‐__b__‐PFS precursors. Well‐defined materials
## Abstract **Summary:** Triblock copolymers of methyl methacrylate (MMA) and 2‐ethylhexyl methacrylate (EHMA) [that is, poly(MMA–EHMA–MMA)] were prepared by an emulsion atom‐transfer radical polymerization. The relationships of their structural, morphological, and physical properties were investig
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