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Synthesis and bond isomerization of 3-carbethoxyhepta-3,5-dien-2-one

✍ Scribed by Zh. A. Krasnaya; E. P. Prokof'ev; V. F. Kucherov

Book ID
112423608
Publisher
Springer
Year
1970
Tongue
English
Weight
497 KB
Volume
19
Category
Article
ISSN
1573-9171

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Synthesis and oxidation of pregna-3,5-di
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✍ Göndös, György ;Orr, James C. 📂 Article 📅 1990 🏛 John Wiley and Sons 🌐 English ⚖ 248 KB

## Abstract Pregna‐3,5‐dien‐20‐one (4) and (20S)‐ and (20R)‐pregna‐3,5‐dien‐20‐ol (2 and 3) were synthesized from progesterone. Oxidation of a mixture of 2 and 3 with Jones reagent gave 4, while a large excess of Jones reagent afforded besides 4, 6‐oxoprogesterone (5), 6β‐hydroxyprogesterone (6) an