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Synthesis and biological activity of brassinolide and its 22β,23β-isomer: Novel plant growth-promoting steroids

✍ Scribed by Malcolm J. Thompson; N.Bhushan Mandava; Werner J. Meudt; William R. Lusby; David W. Spaulding

Book ID
118978834
Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
776 KB
Volume
38
Category
Article
ISSN
0039-128X

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Stereoselective synthesis of a new hexanor(C23-C28)castasterone-20,22-ethyl diether 2~ has been achieved in sixteen steps from cheap and readily available 16-dehydropregnenolone acetate. This new brassinosleroid has shown typical brassin activity in mung bean epicotyl bioassay.

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Stereoselective Synthesis of a New Hexanor(C23-C28)castasterone-20,22-ethyl Diether from 16-Dehydropregnenolone Acetate and Its Plant Growth Promoting Activity. -The new brassinosteroid (IX) is stereoselectively synthesized starting from readily available acetate (I). It shows typical brassin activ