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Synthesis and binding studies of the 116-mer peptide containing the double cysteine-rich motifs of protein kinase C gamma

✍ Scribed by Hiroyuki Fukuda; Kazuhiro Irie; Akifumi Nakahara; Kentaro Oie; Hajime Ohigashi; Paul A Wender


Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
259 KB
Volume
39
Category
Article
ISSN
0040-4039

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✦ Synopsis


The 116-mer peptlde contaaning the double cysteine-nch motifs of mouse protein kinase Cy (y-C 1A-C IB) has been synthesized using an Fmoc-solid phase strategy with a stepwise chain elongation. The peptide was purified only by reversed phase HPLC and gave satisfactory mass data (MALDI-TOF-MS and ESI-TOF-MS). Scatchard analysis of the zinc-folded pepUde revealed two binding sites of distinct affinities (Kd = 6.0 and 47.0 nM) comparable to those reported by Quest and Bell for GST-y-C 1A-C 1B fusion protein prepared by DNA recombination.