Synthesis and Cation Binding Properties of Triester Calix[4]arenes and Calix[4]quinones. -The triester methyl calix[4]arene shows the highest extraction of sodium ion. -(NAM, K.
Synthesis and binding properties of calix[4]arene telomers
β Scribed by Aytan Yilmaz; Shahabuddin Memon; Mustafa Yilmaz
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- English
- Weight
- 123 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0887-624X
No coin nor oath required. For personal study only.
β¦ Synopsis
Two calix[4]
arene derivatives (5 and 8) and their telomers are synthesized to estimate selective extraction of alkali and transition metal cations from the aqueous to the organic phase (chloroform). Compound 5 shows selectivity toward Hg 2Ο© . Compound 8 and telomers 6 and 9 are not selective but are good extractants for all used transition metal ions. The observations suggest that ethylene glycol bridges are efficient for carrying transition metal cations in a two-phase solvent system.
π SIMILAR VOLUMES
## Abstract The new chromophore compounds with NLO properties were prepared by Knoevenagel condensation from formyl or diformyl calix[4]arene and isophorone derivatives in the presence of piperidine and acetic acid, respectively. In these chromophore calix[4]arenes, the ring locked trienes were emp