Synthesis and aqueous phase behaviour of homo- and copolymers of 1,1-diallyl-4-formylpiperazinium chloride

✍ Scribed by Sk. Asrof Ali; S. Zaka Ahmed; M.I.M. Wazeer; Esam Z. Hamad

• Book ID: 104164577
• Publisher: Elsevier Science
• Year: 1997
• Tongue: English
• Weight: 944 KB
• Volume: 38
• Category: Article
• ISSN: 0032-3861
• DOI: 10.1016/s0032-3861(96)00893-2

✦ Synopsis

The quaternary ammonium salt, l ,l-diallyl-4-formylpiperazinium chloride (3) on cyclopolymerization in water solution in the presence of t-butylhydroperoxide gave water soluble polymer ( 5). The copolymers of (3) with sulfur dioxide have been prepared in DMSO solvent using ammonium persulfate as the initiator. The composition and phase diagram of the aqueous two-phase systems of the homopolymer (5) and copolymer ( 8) has been studied for the first time for this class of polymers. Synthesis of the polymer (8) paves the way for the preparation of a new class of polymers with a basic trivalent nitrogen as well as a quaternary nitrogen.