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Synthesis and applications to asymmetric catalysis of a series of mono- and bis(diazaphospholidine) ligands

โœ Scribed by Smyth, Donald; Tye, Heather; Eldred, Colin; Alcock, Nathaniel W.; Wills, Martin


Book ID
121409396
Publisher
Royal Society of Chemistry
Year
2001
Weight
579 KB
Volume
21
Category
Article
ISSN
1472-7781

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Synthesis and application to asymmetric
โœ Christopher W Edwards; Mark R Shipton; Nathaniel W Alcock; Howard Clase; Martin ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 214 KB

The synthesis of a series of substituted monodonor diazaphospholidine ligands is described. A regioselective lithiation process is a key step in one of these syntheses. The compounds are designed to be incorporated into soluble polymer and other solid phase supports. Enantiomeric excesses of up to 8