The effect of different N-pentyl-2-pyridylmethanimine derivatives 2a-f upon the rate of copper(I) mediated atom transfer radical cyclisation (ATRC) of 5 and living atom transfer radical polymerisation (ATRP) of methylmethacrylate were investigated.
Synthesis and Application of New Guanidine Copper Complexes in Atom Transfer Radical Polymerisation
✍ Scribed by Olga Bienemann; Roxana Haase; Anton Jesser; Tanja Beschnitt; Artjom Döring; Dirk Kuckling; Ines dos Santos Vieira; Ulrich Flörke; Sonja Herres-Pawlis
- Book ID
- 102828330
- Publisher
- John Wiley and Sons
- Year
- 2011
- Tongue
- English
- Weight
- 804 KB
- Volume
- 2011
- Category
- Article
- ISSN
- 1434-1948
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📜 SIMILAR VOLUMES
The synthesis and characterisation of a series of novel arrangement of co-ordinating nitrogen atoms surrounding the metal centre. All of the catalysts were found to be bis(imine)copper(I) complexes and their use in atom-transfer polymerisation of methyl methacrylate is described. Several effective a
The atom transfer radical polymerization (ATRP) of styrene has been studied using complexes of copper carboxylates. Compared with systems employing copper halides as the catalyst, the use of copper carboxylates resulted in faster polymerization rates and higher polydispersities. A ligand (dNbpy) to
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