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Synthesis and application of new chiral bidentate phosphine, 2,7-di-tert-butyl-9,9-dimethyl-4,5-bis(methylphenylphosphino)xanthene

✍ Scribed by Yasumasa Hamada; Fumiyoshi Matsuura; Makoto Oku; Keiichiro Hatano; Takayuki Shioiri


Book ID
104258376
Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
268 KB
Volume
38
Category
Article
ISSN
0040-4039

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✦ Synopsis


New optically active bidentate phosphines, (S,S)-and (R,R)-2,7-di-tertbutyl-9,9-dirnethyl-4,5-bis(methylphenylphosphino)xanthenes ((S, S)-I and (R, R)-I), were prepared through resolution of the corresponding phosphine oxides using (R, R)-(-)-dibenzoyl-tartaric acid and a preliminary experiment on asymmetric synthesis using an allyl substrate proved the utility of the new bidentate phosphines.


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ChemInform Abstract: Synthesis and Spect
✍ Jian-yong Hu; Arjun Paudel; Takehiko Yamato 📂 Article 📅 2009 🏛 John Wiley and Sons ⚖ 23 KB 👁 1 views

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