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Synthesis and application of dicationic ionic liquids

โœ Scribed by Qingbin Liu; Fred van Rantwijk; Roger A Sheldon


Publisher
Wiley (John Wiley & Sons)
Year
2006
Tongue
English
Weight
101 KB
Volume
81
Category
Article
ISSN
0268-2575

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โœฆ Synopsis


Abstract

Ionic liquids were synthesised that consisted of two methylimidazolium rings joined by a spacer 1โ€“12 carbon atoms in length. The bis(triflic)imides with spacer โ‰คC~4~ were solids; the others were liquid at room temperature. The polarity of the dication liquids and their performance in the extraction of phenol from water were compared with those of similar monocationic liquids. Copyright ยฉ 2005 Society of Chemical Industry


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## Abstract Highest heat of vaporization yet: The dicationic ionic liquid [C~3~(C~1~Im)~2~][Tf~2~N]~2~ evaporates as a neutral ion triplet. These neutral ion triplets can then be ionised to form singly and doubly charged ions. The mass spectrum exhibits the dication attached to one remaining anion,

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