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Synthesis and application of a novel bisphosphine ligand, (−)-DIOCP, as an unsymmetrized diop to prove the general utility of new designing concept.

✍ Scribed by Mitsuo Chiba; Hitoe Takahashi; Hisashi Takahashi; Toshiaki Morimoto; Kazuo Achiwa


Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
201 KB
Volume
28
Category
Article
ISSN
0040-4039

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✦ Synopsis


A new chiral bisphosphine-Rh complex (DIOCP-Rh) was found to show excellent catalytic activity and good enantioselectivity for the asymmetric hydrogenation of ketopantolactone proving the general utility of new designing concept.