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Synthesis and antiproliferative activity of the heterobimetallic complexes [RuClCp(PPh3)-μ-dmoPTA-1κP:2κ2N,N′-MCl2] (M = Co, Ni, Zn; dmoPTA = 3,7-dimethyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane)

✍ Scribed by Serrano-Ruiz, Manuel; Aguilera-Sáez, Luis Manuel; Lorenzo-Luis, Pablo; Padrón, José M.; Romerosa, Antonio

Book ID
121191453
Publisher
Royal Society of Chemistry
Year
2013
Tongue
English
Weight
515 KB
Volume
42
Category
Article
ISSN
1477-9226

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Stepwise introduction of the potential tripod ligands tris(3,5-dimethyl-1-pyrazolyl)borate (Tp\*) and tris(1cyclohepta-2,4,6-trienyl)phosphane into the coordination sphere of rhodium(I) leads mainly to [Tp\*Rh{P(C 7 H 7 ) 3 }] (4), in which Tp\* is linked to the rhodium through a single pyrazolyl gr