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Synthesis and absolute configuration of (+) α-hydroxymethyltyrosine by X-ray analysis of its N-benzoyl derivative

✍ Scribed by Wanda Wieczorek; Maria Bukowska-Strzyżewska; Mirosław T. Leplawy; Aleksandra Olma

Publisher
Springer
Year
1991
Tongue
English
Weight
458 KB
Volume
21
Category
Article
ISSN
1572-8854

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Cα-hydroxymethyl methionine: synthesis,
Cα-hydroxymethyl methionine: synthesis, optical resolution and crystal structure of its (+)-Nα-benzoyl derivative
✍ Renata Witkowska; Krzysztof Kaczmarek; Marco Crisma; Claudio Toniolo; Janusz Zab 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 113 KB

## Abstract (__R__,__S__)‐Methionine was transformed into __C__^α^‐hydroxymethyl methionine by a route involving __C__^α^‐hydroxymethylation of 2‐phenyl‐4‐methylthioethyl‐5‐oxo‐4,5‐dihydro‐1,3‐oxazole. The absolute configuration of (−)‐__C__^α^‐hydroxymethyl methionine was elucidated to be (__S__)