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Synthesis and absolute configuration of sordidin, the male-produced aggregation pheromone of the banana weevil, Cosmopolites sordidus

✍ Scribed by Kenji Mori; Tôru Nakayama; Hirosato Takikawa


Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
203 KB
Volume
37
Category
Article
ISSN
0040-4039

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Pheromone Synthesis, CLXXXIV. Synthesis
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## Abstract The racemate as well as both the enantiomers of sordidin (1‐ethyl‐3,5,7‐trimethyl‐2,8‐dioxabicyclo[3.2.1])octane were synthesized, and the natural pheromone was shown to be (1__S__,3__R__,5__R__,7__S__)‐(+)‐1.

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First Asymmetric Synthesis of (+)-Sordid
✍ Dieter Enders; Irene Breuer; Anja Nühring 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 137 KB

## Abstract The asymmetric synthesis of (1__S__,3__R__,5__R__,7__S__)‐(+)‐sordidin and 7‐__epi__‐(1__S__,3__R__,5__R__,7__R__)‐(–)‐sordidin, both components of the natural male‐produced aggregation pheromone of the banana weevil __Cosmopolites sordidus__ (Germar), starting from 2,2‐dimethyl‐1,3‐dio

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✍ Mary T Fletcher; Christopher J Moore; William Kitching 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 131 KB

Male-specific volatile components released by the banana weevil, Cosmopolites sordidus Gen~ar, from Australia have been identified as (1S,3R,5R,7S)-1 -ethyl-3,5,7-trimethyl-2,8-dioxabieyclo[3.2.1 ]octane and the 7R-epimer (as a minor component) by synthesis and enantioseleetive gas chromatography.