Synthesis and absolute configuration of (−)-chettaphanin I and (−)-chettaphanin II
✍ Scribed by I.S Marcos; F.A Hernández; M.J Sexmero; D Dı́ez; P Basabe; A.B Pedrero; N Garcı́a; J.G Urones
- Publisher
- Elsevier Science
- Year
- 2003
- Tongue
- French
- Weight
- 328 KB
- Volume
- 59
- Category
- Article
- ISSN
- 0040-4020
No coin nor oath required. For personal study only.
✦ Synopsis
efficient synthesis of chettaphanin I and II has been achieved from ent-halimic acid. The absolute configuration of the natural products was established by nOe experiment and by X-ray analysis of chettaphanin II.
📜 SIMILAR VOLUMES
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
pu-t o f project No. SR 2.120.0!, ctf the Schweizerischer Nak~oitalfonds. Financial .4-GEIGY S.A., Easel, is gratefully aclinowlctlgcd. Finally we wish t o thank S A A ~D O Z AG fur t h e gift of computer time. :Ippendix. Table 4 lists t h c analysis of the vilrational fine structure ol ba~icls &,
Enantiospecific syntheses of (+)-and (-)-edulans I, II and (-)-dihydroedulans I, II, starting from (R)-and (S)-3-hydroxybutyric acid methyl esters, allowed the determination of the absolute configurations of edulans I, II.