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Synthesis and 3He NMR Studies of C60 and C70 Epoxide, Cyclopropane, and Annulene Derivatives Containing Endohedral Helium

✍ Scribed by Smith, Amos B.; Strongin, Robert M.; Brard, Laurent; Romanow, William J.; Saunders, Martin; Jimenez-Vazquez, Hugo A.; Cross, R. James


Book ID
127385354
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
573 KB
Volume
116
Category
Article
ISSN
0002-7863

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Bis-to hexakisadducts of C,, (1-6) and mono-to tetrakisadducts of C,, (7-13) containing 'He atoms (endohedral helium complexes) were prepared and studied by 3He NMR spectroscopy to determine the influence of degree of functionalization and addition pattern on the chemical shift of the 'He atom. In t