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Synthesis and 13C, 29Si, 199Hg nuclear magnetic resonance spectroscopy of alkynyl(trimethylsilyl)mercurials

✍ Scribed by Angelika Sebald; Bernd Wrackmeyer

Publisher: Elsevier Science
Year: 1986
Tongue: English
Weight: 370 KB
Volume: 42
Category: Article
ISSN: 1386-1425
DOI: 10.1016/0584-8539(86)80063-0

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✦ Synopsis

Alkynyl(trimethylsilyl)

mercuriaB are formed by a fast and quantitative reaction between bis(alkynyl)-and bis(trimethylsilyl)me.rcury in chloroform or benzene at ambient temperature. They decompose slowly in solution to alkynyltrimethylsilanes and mercury. r3C, x%i, rg9Hg NMR data serve for the characterization. The polarixability of the Hg-Si bond and the great polarizing ability of the alkynyl group is clearly reflected by the NMR data.

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